Thiophene-based poly(arylene ether)s: 5. Imide-arylene ether statistical copolymers
1994
Abstract Imide-aryl ether thiophene copolymers were prepared and their thermal and mechanical properties were investigated. A key feature of these copolymers is the incorporation of the 2,5-thiophene moiety using 5,5′-bis[(3-aminophenoxy)thienyl-2] Ketone or 5,5′-bis[(4-aminophenoxy)thienyl-2] ketone as diamines in polyimide syntheses. The preparation of these thiophene diamines involved the nucleophilic aromatic substitution of bis(5-chlorothienyl-2) ketone with either 3- or 4-aminophenol in N -methyl-2-pyrrolidinone using potassium carbonate. These diamines were reacted with various compositions of pyromellitic dianhydride and 4,4′-oxydianiline to synthesize the desired poly(amic acid)s. Films were cast and cured (300°C) to effect the imide formation, and the resulting films showed tough ductile mechanical properties with high glass transition temperatures that decreased with increasing thiophene diamine content.
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