Piezoelectric Tantalum Aluminum Nitride Films for Vibrational Micro Energy Harvesters

2021 
This paper reports the first attempt to apply highly piezoelectric Ta-doped AlN thin films for vibration-driven micro energy harvesters. Ta x Al 1-x N (x = 0.068) films were grown on Pt/Ti/Si substrates and applied to microfabricate energy harvesters. The Ta-AlN films exhibit a highly c-axis crystal orientation and good electrical properties with low leakage current density of 0.2×10-6 A/cm2 and low loss tangent of 0.02. Our prototype of the Ta-AlN based micro energy harvesters shows the normalized power density (NPD) of 13.7 mW.g-2.cm-3. This result was an approximately 6-fold increase compared to the best of the published pure AlN harvesters and outperformed the PZT-based ones. Also, our first attempt is approaching to the best-published performance of the higher co-dopant concentration (MgHf) 0.11 Al 0.89 N and Sc 0.43 Al 0.57 N.
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