Plasma Enhanced Catalytic Reduction of Nox in Simulated Lean Exhaust

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 25% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K with the highest activity observed at 773K. Examination of this large temperature window has shown that optimum CH:NOx ratio changes with temperature. In general, as temperature increases a larger concentration of propene is required in the exhaust stream because substantial plasma oxidation of propene takes place at lower specific energy. In addition, better NOx reduction efficiency of the catalysts at higher temperature results in additional propene demand. In contrast, the electrical energy required for maximum conversionmore » of NO to NO decreases at high temperature. This mix of observations leads to a hypothesis that as temperature increases there is a tradeoff between electrical energy for conversion of NO to NO and the hydrocarbon levels required to maximize selective catalytic reduction.« less