Double-Morphology CoS2 Anchored on N-Doped Multichannel Carbon Nanofibers as High-Performance Anode Materials for Na-Ion Batteries
2018
Na-ion batteries (NIBs) have attracted increasing attention given the fact that sodium is relatively more plentiful and affordable than lithium for sustainable and large-scale energy storage systems. However, the shortage of electrode materials with outstanding comprehensive properties has limited the practical implementations of NIBs. Among all the discovered anode materials, transition-metal sulfide has been proven as one of the most competitive and promising ones due to its excellent redox reversibility and relatively high theoretical capacity. In this study, double-morphology N-doped CoS2/multichannel carbon nanofibers composites (CoS2/MCNFs) are precisely designed, which overcome common issues such as the poor cycling life and inferior rate performance of CoS2 electrodes. The conductive 3D interconnected multichannel nanostructure of CoS2/MCNFs provides efficient buffer zones for the release of mechanical stresses from Na+ ions intercalation/deintercalation. The synergy of the diverse structural feat...
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