BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
2020
A general and straightforward
method for the synthesis of COO-BODIPYs
from F-BODIPYs and carboxylic acids is established. The method is
based on the use of boron trichloride to activate the involved substitution
of fluorine, which leads to high yields through rapid reactions under
soft conditions. This mild method opens the way to unprecedented laser
dyes with outstanding efficiencies and photostabilities, which are
difficult to obtain by the current methods.
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