Pressure-induced Phase Changes in Cesium Lead Bromide Perovskite Nanocrystals with and without Ruddlesden-Popper Faults

Lead halide perovskites have a rich landscape of structural and optical properties, which can be explored and possibly controlled by applying high pressure. Despite several reports on high pressure studies of CsPbBr3 nanocrystals (NCs), there have so far been no studies under pressure that incorporate planar defects. CsPbBr3 NCs with Ruddlesden-Popper faults (RP), formed via post-synthetic fusion growth, are significantly larger in size than as-synthesized NCs and display exceptional emission stability. Here, we compare synchrotron-based high pressure X-ray diffraction and photoluminescence (PL) properties of CsPbBr3 (without RP) and RP-CsPbBr3 (with RP), and resolve their crystal structure under pressure for the first time. CsPbBr3 undergoes a phase transition from orthorhombic Pnma phase at ambient pressure to cubic Pm3 m phase at 1.7 GPa and RP-CsPbBr3 transforms from Pnma to the monoclinic P21/m phase at 0.74 GPa in addition to several isostructural transitions. Density-functional calculations predic...