Nanocomposites of TiO2 and double-walled carbon nanotubes for improved dye-sensitized solar cells

2012 
It is demonstrated that an incorporation of double-walled carbon nanotubes (DWCNTs) into a TiO2 photo-anode layer results in a significant improvement in the overall energy conversion performance in the dye-sensitized solar cell (DSSC). Comparing to the standard TiO2 anode, the carbon nanotube-containing TiO2 anode with 0.2 wt. % DWCNTs has boosted up the photocurrent density (Jsc) by 43%. The DSSC power conversion efficiency was also improved from ∼3.9% in the case of carbon nanotube-free TiO2 anode to as high as 6.4% with the addition of DWCNTs upon optimized anode annealing. The observed enhancement in the solar cell performance in the presence of the carbon nanotubes is attributed primarily to the noticeable reduction in microcracking and associated robust electrical conduction. Some contribution of the electrical conducting nature of the filler material (DWCNTs) to the improved DSSC properties may be possible; however, it is viewed as a minor effect, considering the small amount of the nanotubes used.
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