Effect of heat treatment on magnetic properties and morphology of iron particles

Acicular iron particles with high coercivity and high saturation magnetization were prepared by reduction of the hematite particles which were obtained by dehydration of the silica‐coated goethite particles in the process of heat treatment in air. Variations in specific surface area, micropore distribution, crystallite size, and magnetic properties with the dehydration temperature were measured. For the iron particles prepared by reduction of the silica‐coated hematite particles obtained by dehydration at 800 °C, a maximum coercivity of 1250 Oe was obtained, and the crystallite size reached the minimum value of 220 A which was close to the critical value of single domain particle. The highly acicular iron particles consisting of the closely packed small crystallites were obtained.