Combination of acid-resistor and -scavenger improves the SEI stability and cycling ability of tin–nickel battery anodes in LiPF6-containing electrolyte
2013
Abstract Control of electrode–electrolyte interfacial reactivity and the formation of the solid electrolyte interphase (SEI) layer is a key technology for high performance rechargeable lithium batteries. Here we present the first report on a promising interfacial approach for Sn–Ni electrode that the use of acid-resisting and -scavenging fluorine-dopant on Sn combined with acid-scavenging trimethyl phosphite electrolyte additive to LiPF 6 -contiaing carbonate-based organic electrolyte improves the interfacial stability of Sn to acidic electrolyte species. As a result, a stable SEI layer consisting of a plenty of carbonate decomposition products forms and cycling ability significantly improves, in contrast to less efficient SEI formation and rapid performance fade for the electrodes without fluorine-dopant or trimethyl phosphite additive.
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