Determination of phenols in water by on-line solid-phase disk extraction and liquid chromatography with electrochemical detection

Abstract Poly(styrene-divinylbenzene) (PS-DVB) membrane extraction disks were used as sorbents for the on-line solid phase extraction of 13 phenols (nitro and chlorophenols) in river and tap waters. Determination was performed by liquid chromatography with electrochemical detection (LC-ED). An acetate buffer-acetonitrile-methanol mixture as mobile phase and amperometric detection at +1100 mV were used. High water volumes, up to 250 ml, can be preconcentrated without loss of phenols (recoveries between 80% and 100%) except for the more polar ones. Moreover, detection limits between 0.01 and 0.1 μg l −1 in tap water and between 0.1 and 1.0 μg −1 in river water were obtained. The method has been applied to the analysis of two river water samples.