Coherent spin rotation-induced zero thermal expansion in MnCoSi-based spiral magnets

Materials exhibiting zero thermal expansion (ZTE), namely, volume invariance with temperature change, can resist thermal shock and are highly desired in modern industries for high-precision components. However, pure ZTE materials are rare, especially those that are metallic. Here, we report the discovery of a pure metallic ZTE material: an orthorhombic Mn1-xNixCoSi spiral magnet. The introduction of Ni can efficiently enhance the ferromagnetic exchange interaction and construct the transition from a spiral magnetic state to a ferromagnetic-like state in MnCoSi-based alloys. Systematic in situ neutron powder diffraction revealed a new cycloidal spiral magnetic structure in the bc plane in the ground state, which transformed to a helical spiral in the ab plane with increasing temperature. Combined with Lorentz transmission electron microscopy techniques, the cycloidal and helical spin order coherently rotated at varying periods along the c-axis during the magnetic transition. This spin rotation drove the continuous movement of the coupled crystalline lattice and induced a large negative thermal expansion along the a-axis, eventually leading to a wide-temperature ZTE effect. Our work not only introduces a new ZTE alloy but also presents a new mechanism by which to discover or design ZTE magnets. The introduction of minimal Ni into MnCoSi efficiently changes the magnetic interaction and establish a thermal-induced magnetic transition from a spiral magnetic state to a ferromagnetic-like state in Mn1-xNixCoSi alloys. With increasing the temperature, both the cycloidal and helical magnetic spin rotates continuously and coherently towards to b axis during the transition. Therefore, a wide-temperature range zero thermal expansion behaviour is realized owing to the robust magnetoelastic coupling.