Effect of ultrasound on the morphology of the CaCO3 precipitated from CaSO4-NH3-CO2-H2O system ☆

Abstract Micron-grade calcium carbonate (CaCO 3 ) crystals are by-products in the preparation of (NH 4 ) 2 SO 4 fertilizer using CaSO 4 ·2H 2 O, NH 3 , and CO 2 . Since ultrasound can make crystals smaller and their morphology quite complex, the morphological change rules need to be studied to make meaningful use of them. In the present work, the morphologies of CaCO 3 crystals precipitated from the ultrasound CaSO 4 -NH 3 -CO 2 -H 2 O system were analyzed in different conditions. It was found that ultrasound can make the crystals smaller in nucleation or the early growth stage, or it can make the shapes diversified and dispersed by influencing the solution property and in the aging process. In an ultrasound environment, crystals may be square, spheroidal, ellipsoidal, pisciform (spindle), hexagonal, carambola-like, or scattered particles. High-concentrations of NH 3 and CO 2 facilitate CaCO 3 crystals becoming smooth balls, while high-intensity ultrasound and a high-concentration of foreign Na + ions help to turn CaCO 3 into tiny square particles or a clustered aggregate of tiny particles with rough surfaces.