A New Chiral Iminophosphine Ligand Derived from (1S,4S)-Fenchone in Palladium-Catalyzed Asymmetric Allylic Alkylations.

Abstract A new chiral iminophosphine ligand derived from (1 S ,4 S )-fenchone has been developed, and its usefulness as a chiral ligand in asymmetric synthesis was demonstrated in palladium-catalyzed allylic alkylations.