Palladium(II)/Broensted Acid‐Catalyzed Enantioselective Oxidative Carbocyclization—Borylation of Enallenes.

Tuo Jiang,Teresa Bartholomeyzik,Javier Mazuela,Jochen Willersinn,Jan‐E. Baeckvall

Palladium(II)/Broensted Acid‐Catalyzed Enantioselective Oxidative Carbocyclization—Borylation of Enallenes.

2015

Tuo Jiang
Teresa Bartholomeyzik
Javier Mazuela
Jochen Willersinn
Jan‐E. Baeckvall

An oxidative cyclization of allenes in the presence of (Bpin)2 is developed using p-benzoquinone as the oxidant and Pd(OAc)2 and an axially chiral bisphenol-type phosphinic acid as catalysts.

Keywords:

Enantioselective synthesis
Palladium
Catalysis
Borylation
Organic chemistry
Chemistry
Chirality (chemistry)
Oxidative phosphorylation
acid catalyzed
oxidative cyclization

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