Synthesis of Amidines Using N-Allyl Ynamides. A Palladium- Catalyzed Allyl Transfer Through an Ynamido-π-Allyl Complex

A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-π-allyl complexes.