Controlled Trifluoromethylation Reactions of Alkynes Through Visible‐Light Photoredox Catalysis.

Naeem Iqbal,Jaehun Jung,Sehyun Park,Eun Jin Cho

Controlled Trifluoromethylation Reactions of Alkynes Through Visible‐Light Photoredox Catalysis.

2014

Naeem Iqbal
Jaehun Jung
Sehyun Park
Eun Jin Cho

Three different CF3-substituted compounds - trifluoromethylated alkenyl iodides, alkenes, and alkynes - can be selectively generated from terminal alkynes and CF3I by appropriate choice of catalyst, base, and solvent.

Keywords:

Solvent
Catalysis
Trifluoromethylation
Visible spectrum
Photoredox catalysis
Chemistry
Organic chemistry

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