Синтез м -, о -нитро-бензилиден- м -фенилендиаминов и их окислительная полимеризация
2020
New benzylidenphenylenediamines containing azomethine groups were synthesized by condensation of m -, o -nitrobenzaldehyde and m -phenylenediamine. The structure of the obtained benzylidene-phenylenediamines was confirmed by spectral methods and elemental analysis. It was found that benzylidenephenylenediamines irradiated with UV light exhibit luminescent properties. The synthesized benzylidenephenylenediamines are capable of oxidative polymerization to form polymers with conjugated systems. The effects of various factors on the polymerization of benzylidenephenylenediamines were studied. It was established that the obtained polybenzylidenephenylenediamines have noticeable heat resistance and electrical conductivity.
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