Heat transfer enhancement in methanol steam reforming for a fuel cell

Abstract The catalytic methanol steam reforming reaction was investigated by numerical simulation and experiments. Methanol conversion ratio as well as carbon monoxide (CO), which poisons a typical polymer electrolyte fuel cell, increases in a tablet catalyst when temperature is elevated. There is a trade-off relationship between methanol conversion ratio and CO concentration. It was found that the reforming reaction is controlled by heat transfer at large methanol flow rate, where the trade-off relationship shifts to lower methanol conversion ratio and higher CO concentration. To improve the trade-off relationship, internal corrugated metal heater and external catalytic combustion heater were applied to enhance the heat transfer. Optimal cell density for the internal corrugated metal heater, which was about 9×10 5 cell/m 2 , was closely related with reaction parameters such as velocity, cell density, geometric surface area and hydraulic diameter. The catalytic combustion heater is larger than the internal corrugated metal heater in size. Both high methanol conversion ratio and low CO concentration were accomplished by heat transfer enhancement with the two techniques at large methanol flow rate.