Photochemistry of 7-hydroxy-2-(4-hydroxystyryl)-1-benzopyrylium and related compounds.
2009
2-Styryl-1-benzopyrylium derivatives exhibit deeper hues and absorption spectra that are substantially red-shifted when compared with their 2-phenyl-1-benzopyrylium analogues. They follow the same pH and light-dependent network of chemical reactions previously described for 2-phenyl-1-benzopyrylium compounds. In this work, the photochromic properties of 7-hydroxy-2-(4-hydroxystyryl)-1-benzopyrylium chloride are reported. This compound was fully characterized by UV−vis absorption, fluorescence emission, pH jumps, and flash photolysis, and its properties were compared with the analogue 7,4′-dihydroxyflavylium (7-hydroxy-2-(4-hydroxyphenyl)-1-benzopyrylium). The trans-chalcones of both compounds lacking the hydroxyl in position 2 were synthesized and used as model compounds since they exhibit cis−trans isomerization but cannot be involved in the other processes resulting from the ring closure. The transient absorption of two triplets attributed to the chalcones Ct/Ct−, and a tautomer was detected by nanoseco...
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