1D and 2D silver-based coordination polymers with thiomorpholine-4-carbonitrile and aromatic polyoxoacids as co-ligands: structure, photocatalysis, photoluminescence and TD-DFT study

Four silver-based coordination polymers {[Ag(L)2](BF4)}∞ (1), {[Ag(H2BTC)(L)]×(H3BTC)}∞ (2), {[Ag2(H2BTEC)(L)2] × 3.33H2O }∞ (3) and [Ag(H25SSA)(L)]∞ (4) were synthesized using thiomorpholine-4-car...