Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand

Carolin Tschersich,Christian Limberg,Stefan Roggan,Christian Herwig,Nikolaus P. Ernsting,Sergey A. Kovalenko,Stefan Mebs

Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand

2012

Carolin Tschersich
Christian Limberg
Stefan Roggan
Christian Herwig
Nikolaus P. Ernsting
Sergey A. Kovalenko
Stefan Mebs

: Noble metals meet a heavyweight: A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal→bismuth contributions.

Keywords:

Platinum
Photochemistry
Bismuth
Acceptor
Pincer ligand
Chemistry
Inorganic chemistry
donor acceptor

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