catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]

2010 
The title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclear Cu2I2(PPh3)2 units bridged by 3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra­hedral CuI atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra­zine ligand and one terminal triphenyl­phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) A, implying a weak Cu⋯Cu inter­action.
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