1-Methylcycloprop-2-ene-1-carbonitrile in tandem alder-ene and diels-alder reactions

2010 
The reactions of 1-methylcycloprop-2-ene-1-carbonitrile with cyclohexa-1,4-diene and alloocimene gave the corresponding 2:1 addition products as a result of consecutive (conjugate) Alder-ene and Diels-Alder reactions. 1-Methylcycloprop-2-ene-1-carbonitrile acts initially as enophile, and in the second step, as dieno- phile. The structure of the adducts was determined by X-ray analysis.
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