Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ4 O:O′;κ3 O,O′:O;κ3 O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ2 O,O′](1,10-phenanthroline-κ2 N,N′)samarium(III)}
2010
In the dimeric centrosymmetric title complex, [Er2(C10H11O4)6(C12H8N2)2], the ErIII ion is nine-coordinated by five 2-(3,4-dimethoxylphenyl)acetic acid (DMPA) ligands via seven O atoms and two N atoms from a bis-chelating 1,10-phenanthroline (phen) ligand in a distorted tricapped trigonal-prismatic geometry. The DMPA ligands are coordinated to the ErIII ion in bis-chelate, bridging and bridging tridentate modes. Relatively weak intramolecular C—H⋯O interactions reinforce the stability of the molecular structure. Intermolecular C—H⋯O interactions are also observed.
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