Tunable luminescence properties and energy transfer in Ba3Lu(PO4)3:Ce3+,Tb3+ phosphors

Abstract A series of novel color-tunable phosphors Ba 3 Lu(PO 4 ) 3 :Ce 3+ ,Tb 3+ have been synthesized by solid-state reaction. X-ray diffraction, photoluminescence emission and excitation spectra, lifetime, as well as the effect of Tb 3+ concentration were employed to characterize the resulting samples. The emission spectra of Ba 3 Lu(PO 4 ) 3 :Ce 3+ ,Tb 3+ phosphor contains both the asymmetric broad-band Ce 3+ ion emission and the line-type Tb 3+ ion emission. Under ultraviolet light excitation, Ba 3 Lu(PO 4 ) 3 :Ce 3+ ,Tb 3+ can achieve tunable emission from deep blue to yellowish-green by changing the concentration of Tb 3+ . The results indicated that these phosphors could be considered as double emission phosphors for field emission displays.