Thionocarbonat-fixierung durch vib-metallcarbonyle: Chemie, spektroskopie und molekülstruktur

Abstract The pentacarbonyl thionocarbonate metal complexes III, IV, and V are synthesized under photochemical conditions from Cr(CO) 6 , Mo(CO) 6 , W(CO) 6 , and thionocarbonates I in THF. Reactions of the new complexes are described, and spectroscopic properties (IR, NMR, MS, and ESCA) discussed. The crystal structure of IIIa was determined by single crystal X-ray techniques.