Metal‐Free Nitrative Cyclization of N‐Aryl Imines with tert‐Butyl Nitrite: Dehydrogenative Access to 3‐Nitroindoles.

Guo-Bo Deng,Jia‐Ling Zhang,Yan‐Yun Liu,Bang Liu,Xu‐Heng Yang,Jin-Heng Li

Metal‐Free Nitrative Cyclization of N‐Aryl Imines with tert‐Butyl Nitrite: Dehydrogenative Access to 3‐Nitroindoles.

2015

Guo-Bo Deng
Jia‐Ling Zhang
Yan‐Yun Liu
Bang Liu
Xu‐Heng Yang
Jin-Heng Li

The cyclization works well with tert-butyl nitrite only while similar reagents iso-butyl or n-amyl nitrite give preferentially β-nitroethylidene derivatives, e.

Keywords:

Nitration
Butyl nitrite
Aryl
Nitrite
Metal
Chemistry
Reagent
Organic chemistry
tert butyl
metal free

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