The Role of Organoferrates in Iron‐Catalyzed Cross‐Couplings
2020
Recent groundbreaking studies on organoferrates have demonstrated that coordinatively unsaturated three-coordinate-sigma-alkylferrates are active catalysts in Fe-catalyzed cross-couplings with Grignard reagents and that pronounced solvent and counterion effects dictate metalate speciation and catalyst activity. Thanks to modern spectroscopic methods, sensitive catalyst intermediates could be analyzed.
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