Simultaneous synthesis and characterization of in/out-isomers of disilabicyclo[14.14.14]alkanes
2021
Facile and simultaneous synthesis of diphenyl-disilabicyclo[14.14.14]alkane in/out-isomers was achieved by using organosilicon chemistry. Although the formation of several in/out-isomers would be conceivable, only two diastereomers, i.e. the (traditional-)out,out-isomer and the twist-out,out-isomer, could be isolated because of homeomorphic isomerization. Crystal structures of the diastereomers were confirmed.
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