Polyoxometalates Templated Metal Ag–Carbene Frameworks Anodic Material for Lithium-Ion Batteries

A POMs templated 3D Ag–carbene framework with lvt-a topology was hydrothermally synthesized. The POMs templated MCF combining the advantages of POMs, MOFs, and carbene not only shows excellent thermal and chemical stabilities but also possesses a good discharge capacity of 481 mAh·g–1 after 100 cycles applied as anode material in LIBs.