The distillation behavior of fluorides in LiCl–KCl molten salt

The distillation behaviors of some fission product fluorides in LiCl–KCl system were investigated. For rare earth element, the corresponding decontamination factors (DFs) of Ce in 5 wt% CeF3–LiCl–KCl salts were over 100 at 1040 K and 13 Pa. For SrF2, the very poor DFs was deduced for the presence of more volatile SrClF, while Zr4+ was observed to complex easily with F− and Cl−, which affected its evaporation rate and the separation efficiency. F ion concentration in condensate salt was 1–2 level higher than the metal ion due to the stronger covalent band.