Axially chiral electron-rich TunePhos-type ligand: synthesis and applications in asymmetric hydrogenation
2009
A new electron-rich TunePhos type ligand has been synthesized; excellent enantioselectivities (up to 99% ee) have been achieved in Rh-catalyzed asymmetric hydrogenation of α-dehydroamino acid methyl esters and dimethyl itaconate.
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