Crystal Structure and Magnetic Properties of [Cu(4-Me-3-Nit-trz)4](ClO4)2, with 4-Me-3-Nit-trz = 2-(3-[4-Methyl-1,2,4-triazolyl])-4,4,5,5-tetramethylimidazoline-1-oxyl 3-Oxide. Intra- and Intermolecular Spin Interactions
1996
The first two transition metal compounds incorporating triazole−nitronyl−nitroxide radicals as ligands have been synthesized. These compounds are [Cu(4-Me-3-Nit-trz)4](ClO4)2 (1) and [Ni(4-Me-3-Nit-trz)4](ClO4)2 (2) with 4-Me-3-Nit-trz = 2-(3-[4-methyl-1,2,4-triazolyl])-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide. Compound 1 crystallizes in the triclinic system, space group P1. The lattice parameters are a = 9.742(2) A, b = 12.214(12) A, c = 12.981(4) A, α = 67.19(4)°, β = 81.48(2)°, and γ = 79.24(4)°, with Z = 1. The structure consists of centrosymmetrical [Cu(4-Me-3-Nit-trz)4]]2+ cations and noncoordinated perchlorate anions. The Cu(II) ion is in an N4O2 elongated tetragonal environment with two oxygen atoms of two nitroxide groups occupying the apical positions. Within the lattice the cations form infinite chains with short intermolecular contacts involving the nitronyl−nitroxide moieties of two adjacents cations. The temperature dependence of the magnetic susceptibility and the field dependence of ...
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