Lamellar liquid crystals of zwitterionic surfactants with hydrocarbon and polyisobutylene chains

Abstract Surfactants from either polyisobutylene or alkylsuccinic anhydrides derivatized with diethanolamine in a 1:1 molar ratio with hydrocarbon and polyisobutylene chains of similar length formed lamellar liquid crystals in situ and also with added water. The repeat distance between layers was determined using low angle X-ray diffraction (LAXD), and the water penetration into the hydrocarbon space in the lamellar structure was calculated. The results revealed a significantly increased repeat distance for the polyisobutylene chain surfactants compared to the alkyl analogues. The water penetration was significantly greater for a surfactant with a decyl chain compared to the one with a dodecyl chain and was intermediate for the polyisobutylene based surfactant.