Preparation and application of meso-adsorbent NiFe2O4 for the ultrasound-enhanced removal of dye pollutant in water and wastewater

Herein, we present a new combustion method for the preparation of meso-adsorbent NiFe2O4 powders. For the characterization of adsorbent, techniques SEM, XRD, and BET were used. BET measurements confirmed the specific surface area (SSA) 87.7 m2.g-1, the total pore volume (PV) 0.2377 cm3.g-1, and the mean pore size (PS) 10.841 nm. The mean crystallite diameter of the adsorbent using the Scherrer equation was 10 nm. Also, the response surface methodology and artificial neural network models were used for modeling, optimization, and prediction of the responses for removing methyl violet from water and wastewater in lab-scale batches. To study absorption, a four-factor central composite design was used to select the best experimental condition for ultrasonic-assisted adsorption of methyl violet dye. The adjusted R2 of 0.9931 and the predicted R2 of 0.9813 are very close, indicating the compatibility of the experimental results with the quadratic model. According to results, optimum conditions set at ultrasonic time 231 s, 13.5 mg of adsorbent, dye concentration 2.0 mg/L, and pH=7.9. Also, the learning rule of Levenberg–Marquardt was used for ANN Modeling. According to the proposed ANN, the value of root mean square error (RMSE) was 2.562, and the value of correlation coefficient (R2) was 0.986. Also, the good removal efficiency 96.8% and 95.57% were obtained for tap water and wastewater, respectively.