MODELING AND SIMULATION OF ARSENATE FATE AND TRANSPORT IN A DISTRIBUTION SYSTEM SIMULATOR

Multi-species water quality models can be used to predict the fate and transport of contaminants such as arsenic in water distribution networks. In recent work, water quality models have been used to simulate hypothetical contamination events, estimate potential human health effects, and characterize the ability of sensors to detect contamination. Little work has been done to calibrate water quality models and validate them against experimental data generated in Distribution System Simulators (DSSs). In this paper, results are reported from bench scale and pilot scale experiments performed with a DSS at U. S. EPA’s Test and Evaluation Facility in Cincinnati, Ohio. The parameters for a reversible adsorption model were estimated from bench scale data generated over two days. The model was used with the EPANET-MSX software package to simulate the pilot scale experiment in the DSS. Model results match the pilot scale data very well for the first two days after the arsenate injection, however pilot scale data after this time deviates from model predictions. This deviation may be due to limitations in the time scale or sample size of the bench scale experiment. Additional modeling, simulation, and experimental work is planned to develop a fate and transport model that can be used in practical settings to design decontamination strategies following intentional arsenic contamination of water distribution systems.