Stereocontrolled synthesis of calyculin A: construction of the C(26)–C(37) amide-oxazole unit

Anthony G. M. Barrett,Jeremy John Edmunds,James A. Hendrix,James W. Malecha,Christopher J. Parkinson

Stereocontrolled synthesis of calyculin A: construction of the C(26)–C(37) amide-oxazole unit

1992

Anthony G. M. Barrett
Jeremy John Edmunds
James A. Hendrix
James W. Malecha
Christopher J. Parkinson

(–)-B-[3-(Diisopropylaminodimethylsilyl)allyl]diisopinocampheylborane and Cornforth–Meyers chemistry, and Evans alkylation were employed to construct the C(26)–C(37) amide–oxazole unit of calyculin A.

Keywords:

Calyculin A
Alkylation
Diisopinocampheylborane
Calyculin
Oxazole
Chemistry
Amide
Stereochemistry
Organic chemistry

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