1,n‐Rearrangement of Allylic Alcohols Promoted by Hot Water: Application to the Synthesis of Navenone B, a Polyene Natural Product.

Pei-Fang Li,Heng-Lu Wang,Jin Qu

1,n‐Rearrangement of Allylic Alcohols Promoted by Hot Water: Application to the Synthesis of Navenone B, a Polyene Natural Product.

2014

Pei-Fang Li
Heng-Lu Wang
Jin Qu

The 1,n-rearrangement of acyclic and cyclic allylic alcohols under aqueous conditions represents a novel method for the synthesis of various β,γ-unsaturated alcohols.

Keywords:

Allylic rearrangement
Polyene
Navenone B
Natural product
Aqueous solution
Organic chemistry
Chemistry

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