Dissociation dynamics of core excited iron carbonyl‐nitrosyl
2008
Core excitation of a complex molecule like iron carbonyl nitrosyl allows to show that site selective excitation is not necessarily followed by selective fragmentation, probably due to a fast electronic to vibrational energy conversion. The use of multicoincidence electron/ion/ion technique shows however that fragmentation takes place on a much slower time scale allowing stewise processes to be observed.
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