Tridentate Citrate Chelation towards Stable Fiber Zinc-Polypyrrole Battery with Hybrid Mechanism

Abstract The persistent challenge in Zn-ion batteries is the decomposition of coordinated water around Zn2+-induced side reactions and dendrite growth on Zn anode, leading to short lifespans. This situation is even worse in fiber-shaped Zn-ion batteries (FZIBs). Their curved and complex surface structure makes it even challenging to stabilize Zn anode via existing strategies. Herein, we address this dilemma via cost-effective citrate anion (Cit3−) additives which work as a tridentate chelating agent to regulate electrolytes on the molecular level. Synchrotron X-ray absorption fine structure analyses reveal that Cit3− manipulates the solvation shell of Zn2+ by forming [ZnCit(H2O)3]− chelate complexes. Combining with density functional theory calculation, for the first time, we demonstrate that Cit3− facilitates dehydration in [ZnCit(H2O)3]−, passivates remaining coordinated water via mitigating H-O bond (H2O) elongation by 77.7%, suppresses Zn2+ transfer kinetics, homogenizes Zn2+ distribution at interfaces, enabling ∼500% extended lifespan. Based on this, we developed high-performance FZIBs by coupling Zn/carbon fiber anodes with highly conductive polypyrrole/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate fiber (∼3700 S cm−1) cathodes. Further mechanism study suggests that polypyrrole provides extra charge storage capacity by accommodating dual ions, i.e., Zn2+ and SO42−. The obtained quasi-solid-state FZIB possesses excellent performance for practical applications.