The origin of methane in the crust of the Earth

The deposits of hydrocarbons in the crust of the Earth have long been regarded by many investigators as being derived from materials incorporated in the mantle at the time of the Earth's formation. Outgassing processes, active in all geological epochs, then transported the liquids and gases liberated there into porous rocks of the crust. The alternative viewpoint, that biological debris was the source material for crustal hydrocarbons, gained widespread acceptance when molecules of clearly biological origin were found to be usually present in hydrocarbon fluids. Modern information redirects attention to the theories of a nonbiological, primeval origin. Among this information is the prominence of hydrocarbons - gases, liquids, and solids - on many other bodies of the solar system, as well as in interstellar space. Advances in high-pressure thermodynamics have shown that the pressure-temperature regime of the Earth would allow hydrocarbon molecules to be formed and to survive between the surface and a depth of 100 to 300 km. Outgassing from such depth would bring up other gases present in trace amounts in the rocks, thus accounting for the known association of hydrocarbons with helium. Recent discoveries of the widespread presence of bacterial life at depth point to this asmore » the origin of the biological content of petroleum. The carbon budget of the crust requires an outgassing process to have been active throughout the geologic record, and information from planets and meteorites, as well as from mantle samples, would suggest that methane rather than CO[sub 2] could be the major source of surface carbon. Information from deep boreholes in granitic and volcanic rock of Sweden has given support to the theory of the migration of gas and oil from depth, to the occurrence of isotopic fractionation in migration, to an association with helium, and to the presence of microorganisms below 4 km depth. 43 refs., 9 figs.« less