Synthesis, crystal structure and catalytic performance of bis (imino)pyridyl nickel complexes
2007
Two new Ni(II) complexes of 2,6-bis[1-(2,6-diethylphenylimino)ethyl]pyridine (L1), 2,6-bis[1-(4-methylphenylimino)ethyl]pyridine (L2 ) have been synthesized and structurally characterized. Complex Ni(L1)Cl2 · CH3CN (1), exhibits a distorted trigonal bipyramidal geometry, whereas complex Ni(L1)(CH3CN)Cl2 (2), is six-coordinate with a geometry that can best be described as distorted octahedral. The catalytic activities of complexes 1, 2, Ni{2,6-bis[1-(2,6-diisopropyl-phenylimino)ethyl]pyridine} Cl2 · CH3CN (3), and Ni{2,6-bis[1-(2,6-dimethylphenylimino) ethyl]pyridine}Cl2 · CH3CN (4), for ethylene polymerization were studied under activation with MAO.
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