NEUTRAL FOUR-COORDINTE (THIOLATO)- AND (SELENOLATO)IRON(II) COMPLEXES : SYNTHESIS AND CHARACTERIZATION OF FE(E-2,6-I-PR2C6H3)2(1-MEIM)2 (E = S, SE; 1- MEIM = 1-METHYLIMIDAZOLE). POTENTIAL MODELS FOR A BIOLOGICAL, MONONUCLEAR N 2S2 BINDING SITE FOR IRON ?

Cameron E. Forde,Alan. J. Lough,Robert H. Morris,Ravindranath Ramachandran

NEUTRAL FOUR-COORDINTE (THIOLATO)- AND (SELENOLATO)IRON(II) COMPLEXES : SYNTHESIS AND CHARACTERIZATION OF FE(E-2,6-I-PR2C6H3)2(1-MEIM)2 (E = S, SE; 1- MEIM = 1-METHYLIMIDAZOLE). POTENTIAL MODELS FOR A BIOLOGICAL, MONONUCLEAR N 2S2 BINDING SITE FOR IRON ?

1996

Cameron E. Forde
Alan. J. Lough
Robert H. Morris
Ravindranath Ramachandran

The complexes Fe(E-2,6-i-Pr2C6H3)2(1-MeIm)2 (1, E = S; 2, E = Se; 1-MeIm = 1-methylimidazole) are prepared by metathesis of chloride for 2,6-diisopropylbenzenethiolate or -selenolate from iron(II) ...

Keywords:

1-Methylimidazole
Photochemistry
Binding site
Chemistry
Inorganic chemistry
Stereochemistry

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