Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction.

Andreas Gansaeuer,Max Klatte,Gerhard M. Braendle,Joachim Friedrich

Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction.

2013

Andreas Gansaeuer
Max Klatte
Gerhard M. Braendle
Joachim Friedrich

A readily available nontoxic silane is used as terminal reductant for epoxides that are opened by in situ formed bifunctional titanocene(III) hydride catalysts.

Keywords:

Hydrogen atom
Polymer chemistry
Hydride
Catalysis
Bifunctional
Organic chemistry
Silane
Chemistry

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