Advances in Radical Oxidative C—H Alkylation of N‐Heteroarenes

This review summarizes recent development in C—H alkylation of N-heteroarenes via the radical oxidative coupling process. A variety of alkyl radical sources (including alkanes, ethers, alcohols, carboxylic acids, organoboranes, and some other alkane derivatives) for C—H alkylation of N-heteroarenes are reviewed.