Transformation of penicillin sulphoxides into cephalosporins by azo-compounds

Shinji Terao,T. Matsuo,Susumu Tsushima,Norichika Matsumoto,Toshio Miyawaki,M Miyamoto

Transformation of penicillin sulphoxides into cephalosporins by azo-compounds

1972

Shinji Terao
T. Matsuo
Susumu Tsushima
Norichika Matsumoto
Toshio Miyawaki
M Miyamoto

Treatment of penicillin sulphoxides with azocompounds gave cephems (3) in moderate yields together with sulphinyl hydrazodicarboxylates (4) and thiol sulphonates (5).

Keywords:

Penicillin
Thiol
Inorganic chemistry
Chemistry
Cephalosporin
Organic chemistry

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