Origin and Location of Electrons and Protons During the Formation of Intermetalloid Clusters [Sm@Ga3-xH3-2xBi10+x]3- (x = 0, 1).
2015
[K([2.2.2]crypt)]3 [Sm@Ga2HBi11]0.9 [Sm@Ga3H3Bi10] 0.1·en·tol is synthesized from a mixture of [K([2.2.2]crypt)]2[GaBi3]·en and Sm(C5Me4H)3 in en (3 h in the dark) followed by layering with toluene (4 °C, 3 d, 10% yield).
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