Electrophoretic fabrication and pseudocapacitive properties of graphene/manganese oxide/carbon nanotube nanocomposites
2013
Abstract Hybrid nanocomposites provided a synergistic improvement on electrochemical performance and stability for pseudocapacitor. Designed graphene/carbon nanotubes (CNTs)/MnO 2 nanocomposites with CNTs electrode (in short, GMC + C) with highly nanoporous framework surface structure are fabricated by a modified electrophoretic deposition (EPD) method. Scanning electron microscopy and transmission electron microscopy analysis demonstrate that the flake-like MnO 2 thickness (about less than 10 nm) and uniformly distributed on the porous graphene/CNTs framework. X-ray diffraction shows the formation of birnessite-type MnO 2 . Pseudocapacitances of the GMC + C electrode calculated by cyclic voltammetry having different scan rates of 5, 20, 50, 100, and 300 mV s −1 exhibit high specific capacitances of 481, 436, 413, 398, and 372 F g −1 , respectively. Sodium ion diffusion coefficients of the GMC + C electrode show a higher intercalation value of 3.647 × 10 −8 cm 2 s −1 and deintercalation value of 2.899 × 10 −8 cm 2 s −1 using chronoamperometry. Moreover, the GMC + C electrode maintains a high specific capacitance of 346 F g −1 , and is about 83.3% of the initial capacitance after 15,000 charge/discharge cycles. The designed hybrid GMC + C nanocomposites pseudocapacitor electrode using EPD route with the high specific capacitance, fast reaction rate, and high stability, exhibits high potential for practical applications.
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