The Carbonylation of α-Haloacetophenones and Benzyl Halides by Disodium Tetracarbonylferrate

Yoshihisa Watanabe,Kenichi Taniguchi,Masataka Suga,Take-aki Mitsudo,Yoshinobu Takegami

The Carbonylation of α-Haloacetophenones and Benzyl Halides by Disodium Tetracarbonylferrate

1979

Yoshihisa Watanabe
Kenichi Taniguchi
Masataka Suga
Take-aki Mitsudo
Yoshinobu Takegami

α-Haloacetophenones and benzyl chlorides can be converted into derivatives of β-keto acid and phenylacetic acid respectively by two succesive reactions, with Na2-Fe(CO)4 and then with nitrobenzenes or iodine-ethanol as the oxidizing reagents.

Keywords:

Reagent
Disodium tetracarbonylferrate
Halide
Oxidizing agent
Organic chemistry
Carbonylation
Chemistry
Phenylacetic acid
Nitrobenzene

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