Phase Engineering of Hydrophobic Meso-Environments in Silica Particles for Technical Performance Enrichment

Hexadecyltrimethylammonium bromide (CTAB) was utilized to template the growth of mesoporous silica particles via ammonia-catalyzed hydrolysis and condensation of tetraethoxysilane (TEOS) in the reaction solutions with varied volume fractions of ethanol (fR). The use of 9,10-bis(phenylethynyl) anthracene (BPEA) as a fluorescence probe unraveled a clear difference in interior structure between the CTAB micelles confined at different fR. At fR of 0.3, the confined CTAB micelles consisting of regularly and densely packed alkane chains, which created crystalline interiors, in which the doped BPEA molecules were effectively isolated in the monomeric form and well protected against aggressive attack from the surrounding environment. At fR of 0.4 or 0.5, the confined CTAB micelles consisting of less regularly but densely packed alkane chains created glassy interiors, which enabled reversible aggregation of the doped BPEA in response to the surrounding environmental change, for instance, the ethanol content in the...